INVESTIGATION OF THE INHIBITION OF COPPER AND Α-BRASS CORROSION IN NITRIC ACID SOLUTIONS BY PISTACIA ATLANTICA EXTRACT

Authors

  • A. S. Foud Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, Egypt.
  • A. A. Idress Department of Chemistry, Faculty of Science, Omar Almukhtar University, Albayda, Libya.

DOI:

https://doi.org/10.53555/eijas.v6i2.97

Keywords:

Copper, α-Brass, Potentiodynamic polarization, EIS, EFM, SEM

Abstract

The detailed study of Pistacia Atlantica Extract (PAE) as corrosion inhibitor for copper and α-brass in nitric acid solution has been performed through potentio dynamic polarization, electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) measurements. The effect of inhibitor concentration and immersion time against inhibitor action was investigated. Results show that PAE may be used as an efficient inhibitor for copper and α-brass in nitric acid solutions. Potentiodynamic polarization studies reveal that PAE acts as a mixed type inhibitor without any change in the mechanism of hydrogen evolution.

References

. Schweitzer, P., (2010). Fundamentals of Corrosion: Mechanisms, Causes, and Preventative Methods, CRC Press,Taylor and Francis Group, LLC, New York, USA,.

. Ameh, P.O, Oyeniyi, Q.S and Sani, U.M., (2015). Quantum Chemical Studies on the Corrosion Inhibitions of Mild Steel in Acidic Medium by 5-amino-1- cyclopropyl-7-[(3R,5S)-3,5-dimethylpiperazin-1-yl]-6,8-difluoro-4-oxo-1,4dihydroquinoline-carboxylic acid. International Journal of Chemical, Material and Environmental Research, 2 (3): 1

. Bentiss, M., Traisnel, M., and Lagrenee, M., (2001). Influence of 2, 5-bis (4Dimethylaminophenyl)- 1, 3, 4-Thiadiazole on Corrosion Inhibition of Mild Steel in Acidic Media. Journal of Applied Electrochemistry, 31, 41 – 50.

. Ishwara J., Vijaya DPA, (2011). A study of aluminum corrosion inhibition in Acid medium by antiemetic drug. Springer 64(4-5):377-384.

. Obot I.B., and Obi-Egbedi N.O., (2010). Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: Experimental and theoretical investigation. Corros. Sci., 52, 198–204.

. Song P., Guo X.-Y., Pan Y.-C., Shen S., Sun Y., Wen Y., and Yang H.-F., (2013). Insight in cysteamine adsorption behaviors on the copper surface by electrochemistry and Raman spectroscopy. Electrochim, 89, 503–509.

. Ameh, P.O., Oyeniyi, Q.S and Sani, U.M.,( 2015). Quantum Chemical Studies on the Corrosion Inhibitions of Mild Steel in Acidic Medium by 5-amino-1- cyclopropyl-7-[(3R,5S)-3,5-dimethylpiperazin-1-yl]-6,8-difluoro-4-oxo-1,4dihydroquinoline-3- carboxylic acid. Int. J. Chem. Mater. Environ. Res., 2 (3): 1-16.

. Sastri V.S., (1998). Corrosion Inhibitors Principles and Applications. Wiley, Chichester.

. García, S.J., Muster, T.H., Özkanat, Ö. Sherman,. N., Hughes,A.E. ,Terryn,H. J.H.W. de Wit, J.M.C. Mol,( 2010). The influence of pH on corrosion inhibitor selection for 2024-T3 aluminium alloy assessed by high-throughput multielectrode and potentiodynamic testing. ElectrochimicaActa, vol. 55, pp. 2457-2465.

. Roberge,P. R. Handbook of corrosion engineering. New York: McGraw Hill Handbook.

. Arslan, T., Kandemirli, F., Ebenso, E.E., Love, I. and Alemu, H., (1999). Quantum chemical studies on the corrosion inhibition of some sulphonamides on mild steel in acidic medium. Corrosion Science, 2009, 51: 35–47.

. Pang, X., Ran, X., Kuang, F., Xie, J. and Hou, B. (2010). Inhibiting effect of ciprofloxacin, norfloxacin and ofloxacin on corrosion of mild steel in hydrochloric acid. Chinese Journal of Chemical Engineering, 18: 337–345.

. Singh, A.K., Shukla, S.K., Singh, M. and Quraishi, M.A., (2011). Inhibitive effect of ceftadizime on corrosion of mild steel in hydrochloric acid solution. Material, Chemistry and Physics, 129: 68–76.

. Ameh, P.O and Sani, U.M. Cefuroxime Axetil: (2015). A Commercially Available Pro-Drug as Corrosion Inhibitor for Aluminum in Hydrochloric Acid Solution. Journal of Heterocyclics, 101: 1-6.

. Gece, G.,(2011). Drugs: A review of promising novel corrosion inhibitors. Corrosion Science, 53: 3873–3898.

. Mahdi, A.S. (2014). Amoxicillin as green corrosion inhibitor for concrete reinforced steel in simulated concrete pore solution containing chloride, ( IJARET), 5, 99- 107.

. Pathak,R. K. P., Mishra,( 2016). Drugs as Corrosion Inhibitors: A Review. International Journal of Science and Research, Volume 5 Issue 4, 671- 677.

. Scendo, M.,( 2007). Inhibitive action of the purine and adenine for copper corrosion in sulphate solutions. Corrosion Science, 49, 2985–3000.

. Evans, U.R., (1960). The Corrosion and Oxidation of Metals. Arnold, London, p. 324.

. Fenelon, M., Breslin, C.B., (2001). An Electrochemical study of the formation of Benzotriazole surface films on Copper, Zinc and a Copper–Zinc alloy. J. Appl. Electrochem. 31, 509–516.

. Fouda, A.S., Shalabi, K., Elewady, G.Y., Merayyed H.F., (2014). Chalcone derivatives as corrosion inhibitors for carbon steel in 1 M HCl solutions. Int. J. Electrochem. Sci., 9, 7038.

. Fouda, A.S., Shalabi, K., Idress , A.A., (2014). Thymus Vulgarise Extract as Nontoxic Corrosion Inhibitor for Copper and α-Brass in 1 M HNO3. Int. J. Electrochem. Sci., 9, 5126–5154.

. Kertit, S., Essoufi, H., Hammouti, B., Benkaddour, (1998). 1 -phenyl-5-mercaptol, 2, 3,4-tétrazole (PMT) : un nouvel inhibiteur de corrosion de l'alliage Cu-Zn efficace à très faible concentration. M. Chim. Phys. 95, 2070–2082.

. Kliskic M., Radosevic, J., Gndic,S., (1997). Pyridine and its derivatives as inhibitors of aluminium corrosion in chloride solution. J. Appl. Electrochem. 27, 947.

. Li, X.H., Deng, S.D., Fu, H., Mu G.N., (2010). Synergistic inhibition effect of rare earth cerium (IV) ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution, Corros. Sci. 52, 1167.

. Quartarone G., Moretti G., Bellomi T., Capobianco G., Zingales A., (1998). Using Indole to Inhibit Copper Corrosion in Aerated 0.5 M Sulfuric Acid. Corrosion. 54, 606.

. Bjorndahl W.D., Nobe K., (1984). Copper Corrosion in Chloride Media. Effect of OxygenCorrosion. 40, 82.

. R. Schumacher., A. Muller W., Stockel., (1987). An in situ study on the mechanism of the electrochemical dissolution of copper in oxygenated sulphuric acid: An application on the quartz n microbalance. J,Electroanal. Chem. 219, 311.

. Silverman D.C., (1988) Corrosion. Electrochemical Impedance Technique — a Practical Tool for Corrosion Prediction. J.E. Carrico, 44,280.

. W.J. Lorenz, F. Mansfeld., (1981). Determination of corrosion rates by electrochemical DC and AC methods, Corros. Sci. 21 647.

. D.D. Macdonald, M.C. Mckubre.,(1982). Impedance measurements in electrochemical systems, Modern Aspects of Electrochemistry. Vol. 14, Plenum Press, New York, , p. 61

. Mansfeld F., (1981). Recording and Analysis of AC Impedance Data for Corrosion Studies, Corrosion, 36. 130.

. Gabrielli C., (1980). Identification of Electrochemical processes by Frequency Response Analysis. Solarton Instrumentation Group.

. El Achouri M., Kertit S., Gouttaya H.M., Nciri B., Bensouda Y., Perez L., Infante M.R., Elkacemi K., (2001). Corrosion inhibition of iron in 1 M HCl by some gemini surfactants in the series of alkanediyl-α, ω-bis-(dimethyl tetradecyl ammonium bromide). Prog. Org. Coat, 43, 267.

. Macdonald J.R.,. Johanson W.B, (1987). Theory in Impedance Spectroscopy, John Wiley& Sons, New York.

. Mertens S.F., Xhoffer C., Decooman B.C., Temmerman E., (1997). Corrosion Short-Term Deterioration of Polymer-Coated 55% Al-Zn — Part 1: Behavior of Thin Polymer Films. 53, 381.

Downloads

Published

2020-06-27

Issue

Vol. 6 No. 2 (2020): EPH - International Journal of Applied Science ( ISSN: 2208-2182 )

Section

Articles

License

Copyright (c) 2020 EPH - International Journal of Applied Science (ISSN: 2208-2182)

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.