AN EXPERIMENTAL PREPARATION OF FUEL CELL QUATERNARY POLYVINYL BENZYL CHLORIDE (QPVBCL) ALKALINE ANION EXCHANGE MEMBRANE AND INVESTIGATION OF ITS CONDUCTIVITY CHARACTERISTICS

Authors

  • Onyedim, C. N Department of Chemical Engineering and Advanced Materials, Newcastle Upon Tyne University, UK
  • Scott K Department of Chemical Engineering and Advanced Materials, Newcastle Upon Tyne University, UK

DOI:

https://doi.org/10.53555/eijas.v3i2.46

Keywords:

qPVBCl alkaline anion exchange membrane, Conductivity, Conductivity measurement, Alkaline fuel cell.

Abstract

There are different methods of preparing Quaternary polyvinyl benzyl chloride (qPVBCl) alkaline anion exchange membrane. The method which was chosen in this project is simple, relatively cheap and less time-consuming compared to the other methods. This membrane was prepared from a new polymer compound; polyvinyl benzyl chloride (PVBCl). The final membrane is a pale yellow and transparent solid, odourless, flat and smooth with the absence of air bubbles. Through-plane conductivity measurement was performed on qPVBCl alkaline anion exchange membrane and the result showed that the membrane’s conductivity rose from 1.35 x 10-2 S/cm to 1.57 x 10-2 S/cm as temperature increased from 21oC to 61oC. It also showed that the conductivity of the membrane was virtually constant at different periods of time at 61oC. The conductivity was found to be excellent in the fully hydrated condition at optimum temperature 61oC. These results give evidence that the ultimate qPVBCl Alkaline Anion Exchange membrane has enormous potentials for use in alkaline fuel cell.

References

% renewable electricity, a roadmap to 2050 for Europe and North Africa” - www.pwc.co.uk/assets/pdf/100-percent-renewable-electricity.pdf.Viewed: 11/08/2012.

Duncan, C., 2012. “New generation of nuclear reactors could consume radioactive waste as fuel” - http://www.guardian.co.uk/environment/georgemonbiot/2012/feb/02/nuclear.

Yinshi, L., 2011.Characteristics of mass transport in anion - exchange membrane direct ethanol fuel cells. ProQuest Dissertations and Theses, Dissertation, p. 250.

Haile, S. M., 2003. Fuel cell materials and components. Acta Mater, 51, 5981.

E. Gulzow, 1996. Alkaline fuel cells: a critical view. J. Power Sources, 61, 99.

D. Tang, J. Pan, S. Lu, L. Zhuang and J. Lu, 2010. Alkaline polymer electrolyte fuel cells: principle, challenges, and recent progress. Sci. China Chem., 53, 357.

G. F. McLean, T. Niet, S. Prince-Richard and N. Djilali, 2002. An assessment of alkaline fuel cell technology. Int. J. Hydrogen Energy, 27, 507.

S. Lu, J. Pan, A. Huang, L. Zhuang and J. Lu, 2008. Alkaline polymer electrolyte fuel cells completely free from noble metal catalysts. Proc. Natl. Acad. Sci. U. S. A., 105, 20611.

Varcoe, J. R., Slade, R. C. T., 2005. Prospects for Alkaline Anion-Exchange Membranes in Low Temperature Fuel Cells. Fuel Cells 5: 187–200.

Wan, Y., Peppley, B., K., Creber, A. M. and Bui, V. T., 2010. Anion-exchange membranes composed of quaternized-chitosan derivatives for alkaline fuel cells. J. Power Sources, 195, 3785.

Varcoe, J. R., Slade, R. C. T. and Yee, E. L. H., 2006. An electron-beam-grafted ETFE alkaline anion-exchange membrane in metal-cation-free solid-state alkaline fuel cells. Chem. Commun., 8, 839 – 843.

Robertson, N. J., Kostalik, H. A., Clark, T. J., Mutolo, P. F., Abruna, H. D. and Coates, G. W., 2010. Tunable high performance cross-linked alkaline anion exchange membranes for fuel cell applications. J. Am. Chem. Soc., 132, 3400.

Zeng, Q. H., Liu, Q. L., Broadwell, I., Zhu, A. M., Xiong, Y. and Tu, X. P., 2010. Anion exchange membranes based on quaternized polystyrene–block–poly (ethylene–ran– butylene)–block–polystyrene for direct methanol alkaline fuel cells. J. Membr. Sci., 349, 237.

Wang, G., Weng, Y., Chu, D., Chen, R. and Xie, D., 2009. Developing a polysulfonebased alkaline anion exchange membrane for improved ionic conductivity. J. Membr. Sci., 332, 63.

Yuan-Cheng, C., Xu, W., Mohamed, M. and Scott, K., 2011. Preparation of alkaline anion exchange polymer membrane from methylated melamine grafted poly (vinyl benzyl chloride) and its fuel cell performance. J. Mater. Chem., 21, 12910-12916.

Hodakovska, J., Kleperis, J., Grinberga, L., and Vaivars, G., 2009. Conductivity measurement of different polymer membranes for fuel cells. ISSN 1023-1935, Russian Journal of Electrochemistry, vol. 45, no. 6, pp. 656 - 661.

Downloads

Published

2017-06-27